Meanwhile, Sport Recife won 2-1 at Bahia, their third successive Serie A victory. Hernane and Marcao were on the scoresheet for the visitors while Matheus Saldanha netted for Bahia.
Alba had to limp off in the 74th minute and was replaced by new signing Sergino Dest, who played on the left of the Barca defense, despite being right-footed.
James, 29, has also impressed in his opening three matches for Everton in the Premier League following his summer move from Real Madrid.
Raheem Sterling opened the scoring for the visitors in the 17th minute, but Rodrigo Moreno's first goal for Leeds in the 59th minute, following an error from City keeper Ederson Santana saw Marcelo Bielsa's side take a well-deserved point.
The French midfielder fired Marseille in front in the 16th minute from Florian Thauvin's pass, squeezing a shot between goalkeeper Anthony Lopes and the foot of the post for his first goal of the season.
"We heated up quickly into the game, but failed to do enough on defence and rebounds," said Han.
MADRID, Oct. 5 (Xinhua) -- The fifth round of matches in Spain's La Liga takes us into the international break after a frantic three weeks of football. Here are some things we learned in Spain this weekend.
Roma had a shaky start to the new season, managing only one draw and one defeat after two rounds.
World 10,000m bronze medalist Agnes Tirop of Kenya was second in 15:11.11 while Margaret Kemboi also of Kenya taking the third spot In 15:13.38. Ethiopian Tsigie Gebreselama (15:19.79) was fourth.
During the 18-round campaign, teams face lung-busting altitude, scorching tropical heat, long-haul flights between many cities and passionate fans that make stadiums such as Argentina's La Bombonera or Brazil's Maracana among the world's most inhospitable venues for opponents.
Real Madrid faces a tricky visit to play Levante on Sunday evening and there is a feeling that coach Zinedine Zidane still doesn't know what his strongest eleven is. The Frenchman is handicapped by the loss of Eden Hazard, but in attack Zidane has steered away from playing Karim Benzema and Luka Jovic together to using Vinicius Jr and Rodrygo as wingers behind a lone forward.